A Novel all Solid-State Contact PVC-Membrane Beryllium-Selective Electrode Based on 4-Hydroxybenzo-15-Crown-5 Ether Ionophore
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Date
2018
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Publisher
Bentham Science Publ Ltd
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Abstract
Aim: A novel all solid-state contact PVC-membrane beryllium-selective electrode based on 4-hydroxybenzo-15-crown-5 ether as an ionophore is described. Results: The best performance was obtained with a membrane composition of 4% ionophore, 67% dioctyl sebacate (DOS), 28% poly(vinyl chloride) (PVC), and 1% potassium tetrakis (p-chloro) phenylborate (KTClPB) (w/w). The all solid-state contact PVCmembrane beryllium-selective electrode together with an Ag/AgCl reference electrode exhibited sub-Nernstian response with a slope of 22 +/- 1 mV/decade to beryllium ions from 1.0x10(-6) to 1.0x10(-1) M, and resulted a considerably low detection limit of 6.2x10(-7). The electrode had a good performance in selectivity over a wide range of interfering cations tested. It showed a working pH range between 4.0-8.2 with fast response time (< 10 s) and a good reproducibility. Conclusion: The all solid-state contact PVC-membrane beryllium-selective electrode developed was successfully applied in potentiometric titration of Be2+ ions with EDTA.
Description
Demir, Ersin/0000-0001-9180-0609; isildak, ibrahim/0000-0001-9654-1386; Attar, Azade/0000-0001-6906-6989
Keywords
Beryllium-selective electrode, 4-hydroxybenzo-15-crown-5 ether, potentiometry, PVC membrane, ionophore, EDTA
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Fields of Science
Citation
15
WoS Q
Q3
Scopus Q
Q2
Source
Volume
14
Issue
1
Start Page
43
End Page
48