Browsing by Author "Varma, Rajender S."

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MXenes and artificial intelligence: fostering advancements in synthesis techniques and breakthroughs in applications
(Royal Soc Chemistry, 2024) Iravani, Siavash; Khosravi, Arezoo; Zare, Ehsan Nazarzadeh; Varma, Rajender S.; Zarrabi, Ali; Makvandi, Pooyan
This review explores the synergistic relationship between MXenes and artificial intelligence (AI), highlighting recent advancements in predicting and optimizing the properties, synthesis routes, and diverse applications of MXenes and their composites. MXenes possess fascinating characteristics that position them as promising candidates for a variety of technological applications, including energy storage, sensors/detectors, actuators, catalysis, and neuromorphic systems. The integration of AI methodologies provides a robust toolkit to tackle the complexities inherent in MXene research, facilitating property predictions and innovative applications. We discuss the challenges associated with the predictive capabilities for novel properties of MXenes and emphasize the necessity for sophisticated AI models to unravel the intricate relationships between structural features and material behaviors. Moreover, we examine the optimization of synthesis routes for MXenes through AI-driven approaches, underscoring the potential for streamlining and enhancing synthesis processes via data-driven insights. Furthermore, the role of AI is elucidated in enabling targeted applications of MXenes across multiple domains, illustrating the correlations between MXene properties and application performance. The synergistic integration of MXenes and AI marks the dawn of a new era in material design and innovation, with profound implications for advancing diverse technological frontiers.
Citation Count: 0
Next-generation nitrogen fixation strategy: empowering electrocatalysis with MXenes
(Royal Soc Chemistry, 2024) Iravani, Siavash; Khosravı, Arezoo; Khosravi, Arezoo; Varma, Rajender S.; Zarrabi, Ali; Genetik ve Biyomühendislik / Genetic and Bio-Engineering
In recent years, the development of sustainable and cost-effective electrocatalysts for nitrogen (N2) fixation has garnered significant attention, leading to the introduction of next-generation materials with electrocatalytic properties. Among the most interesting types of these materials, MXenes and their composite forms with their unique properties like high electrochemical activity, large surface area, tunable properties, excellent electrical conductivity, chemical stability, and abundant transition metals have been widely explored. These properties make MXenes promising candidates for various electrochemical reactions, including water splitting, oxygen reduction, hydrogen evolution, N2 activation and reduction, among others. The interface of these materials could be engineered with other entities which can serve as a promising tool for sustainable production of ammonia (NH3) to address the global nitrogen-related challenges. Moreover, optimizing the interfaces between them and reactants is another way to achieve high catalytic activity, selectivity, and stability. Accordingly, this review aims to offer a comprehensive overview of the current state of research in the field of electrocatalytic N2 fixation deploying MXenes and their composites. The highlights comprise progress made in understanding the catalytic properties and unique performances of MXenes for N2 fixation, as well as challenges that persist in this context and the possible solutions that could be implemented to circumvent these challenges in the future. MXenes offer environmentally friendly alternatives to conventional N2 fixation methods via potential optimization of their catalytic activity and circumventing some synthesis challenges.
Citation Count: 1
Sustainable synthesis: natural processes shaping the nanocircular economy
(Royal Soc Chemistry, 2024) Khosravi, Arezoo; Khosravı, Arezoo; Iravani, Siavash; Varma, Rajender S.; Zarrabi, Ali; Genetik ve Biyomühendislik / Genetic and Bio-Engineering
Sustainable synthesis in nano domain refers to the development of nanomaterials through deployment of natural processes and principles to minimize the use of hazardous materials and reduce the generation of waste. This method aims to mitigate the environmental impact associated with traditional synthesis methods wherein natural processes, such as biomineralization and self-assembly, offer valuable insights into the nanocircular economy (NE) thus creating numerous benefits. Firstly, it reduces the environmental footprint of nanotechnology by minimizing energy consumption and waste generation. Secondly, it promotes the efficient use of resources by incorporating principles of recycling and reusability. By mimicking natural processes, various nanomaterials can be created, which are biocompatible, biodegradable, and less harmful to the environment. However, challenges such as scale-up, cost, regulatory frameworks, and material selection ought to be addressed to ensure their widespread adoption. The prospects for sustainable synthesis in the NE are promising, with potential advancements in advanced materials, and the integration of circular economy concepts into nanomedicine, and environmental appliances; its future lies in bioinspired synthesis, adherence to green chemistry principles, waste recycling and up-cycling, energy-efficient techniques, life cycle assessment (LCA), and multi-disciplinary collaborations. This review seeks to contribute to the existing knowledge and understanding of sustainable synthesis and its impact on shaping eco-friendlier and resource-efficient NE by describing the methodology involved and discuss the benefits, challenges, and future opportunities emphasizing the importance of sustainability and responsible practices in development of nanomaterials. This perspective aims to shed light on the transformative potential of sustainable synthesis in guiding the transition towards circular economy conceptions in the nanotechnology domain.