Synthesis and boron interaction of new amino acid containing phthalocyanines and the precursor

dc.authorscopusid 55198967300
dc.authorscopusid 23105409900
dc.authorscopusid 35279899900
dc.authorwosid GÜL, Ahmet/B-9622-2013
dc.authorwosid Erdoğmuş, Ali/V-7213-2019
dc.contributor.author Baseren, Sukran Cenikli
dc.contributor.author Erdogmus, Ali
dc.contributor.author Gul, Ahmet
dc.date.accessioned 2024-05-25T11:19:30Z
dc.date.available 2024-05-25T11:19:30Z
dc.date.issued 2018
dc.department Okan University en_US
dc.department-temp [Baseren, Sukran Cenikli; Gul, Ahmet] Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey; [Baseren, Sukran Cenikli] Okan Univ, Pathol Lab Tech Programme, Vocat Sch Hlth Serv, Istanbul, Turkey; [Erdogmus, Ali] Yildiz Tech Univ, Dept Chem, TR-34210 Istanbul, Turkey en_US
dc.description.abstract A new phthalonitrile precursor with tyrosine substituent and the zinc phthalocyanine derived from it were synthesized and their interaction with diphenylborinic acid was studied. The new compounds were characterized by using elemental analysis, IR, H-1 and B-11-NMR and UV-VIS spectral data. B-11-NMR data demonstrated that boron atom attached to the phthalonitrile precursor is in a bulky tetra-coordinated state with the formation of a coordinative N-B bond while completely planar phthalocyanine moieties with high aggregation tendencies at the concentrations used in NMR measurements lead the borinic ester side of the molecule into a planar tri-coordinated form. Moreover, the consequences of the presence of diphenylborinic ester groups on the spectral, photophysical and photochemical properties of the new zinc phthalocyanine are investigated in detail. (C) 2018 Elsevier B.V. All rights reserved. en_US
dc.description.sponsorship Research Fund of the Technical University of Istanbul; Turkish Academy of Sciences (TUBA) en_US
dc.description.sponsorship This work was supported by the Research Fund of the Technical University of Istanbul. AG thanks Turkish Academy of Sciences (TUBA) for partial support. en_US
dc.identifier.citationcount 6
dc.identifier.doi 10.1016/j.jorganchem.2018.04.016
dc.identifier.endpage 111 en_US
dc.identifier.issn 0022-328X
dc.identifier.issn 1872-8561
dc.identifier.scopus 2-s2.0-85046015959
dc.identifier.scopusquality Q3
dc.identifier.startpage 105 en_US
dc.identifier.uri https://doi.org/10.1016/j.jorganchem.2018.04.016
dc.identifier.uri https://hdl.handle.net/20.500.14517/424
dc.identifier.volume 866 en_US
dc.identifier.wos WOS:000432600900013
dc.identifier.wosquality Q2
dc.language.iso en
dc.publisher Elsevier Science Sa en_US
dc.relation.publicationcategory Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı en_US
dc.rights info:eu-repo/semantics/closedAccess en_US
dc.scopus.citedbyCount 7
dc.subject Phthalocyanine en_US
dc.subject Diphenylborinic acid en_US
dc.subject Borinate complex en_US
dc.subject Photochemistry en_US
dc.subject Fluorescence en_US
dc.title Synthesis and boron interaction of new amino acid containing phthalocyanines and the precursor en_US
dc.type Article en_US
dc.wos.citedbyCount 7

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